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The Zhou research group is part of the Miami
University Center for
Nanotechnology
Metal-Organic Frameworks
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Metal-organic frameworks (MOFs) are
microporous zeolite-like networks consisting of metal atoms or clusters
connected by organic ligands |
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Our current research addresses two main
areas:
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Developing novel ligands that lead
to MOFs with increased gas sorption ability (especially methane and H2) |
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Developing novel ligands that lead
to MOFs with chiral channels and/or pores |
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MOFs with chiral channels and functionalized
voids
 
an MOF with increased hydrogen uptake due to
unsaturated metal centers and tailored pores
Research Methods
 | Organic and inorganic synthesis
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standard solution methods |
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solvothermal methods |
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Schlenk and glovebox air- and
moisture-sensitive techniques |
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 | Single-crystal X-ray crystallography
and X-ray powder diffraction |
 | Characterization methods include:
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UV/vis/IR spectroscopy |
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NMR, EPR, and Mossbauer
spectroscopy |
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Fluorescence and photoluminescence
spectroscopy |
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Magnetic susceptibility |
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Cyclic voltammetry |
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Gas adsorption |
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Thermogravimetric analysis |
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 | ab initio and DFT computational
methods |
Current funding for research in the Zhou group comes from the following sources:

NSF
CAREER Grant

Research Corporation: 2003 Research Innovation Award
Research Corporation: 2005 Cottrell Scholar Award

Air Products & Chemicals,
Inc.: 2007
Faculty Excellence Award


Naval Surface Warfare Center, Crane Division
U.S.
Department of Defense

U.S.
Department of Energy

Ohio
Board of Regents

Miami
University
©
2008 Hongcai Joe Zhou All rights reserved
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