Research   
Home

 

The Zhou research group is part of the Miami University Center for Nanotechnology

 

Metal-Organic Frameworks

Metal-organic frameworks (MOFs) are microporous zeolite-like networks consisting of metal atoms or clusters connected by organic ligands

Our current research addresses two main areas:

Developing novel ligands that lead to MOFs with increased gas sorption ability (especially methane and H2)

Developing novel ligands that lead to MOFs with chiral channels and/or pores

 

MOFs with chiral channels and functionalized voids

an MOF with increased hydrogen uptake due to unsaturated metal centers and tailored pores

 

Research Methods

Organic and inorganic synthesis

standard solution methods

solvothermal methods

Schlenk and glovebox air- and moisture-sensitive techniques

Single-crystal X-ray crystallography and X-ray powder diffraction

Characterization methods include:

UV/vis/IR spectroscopy

NMR, EPR, and Mossbauer spectroscopy

Fluorescence and photoluminescence spectroscopy

Magnetic susceptibility

Cyclic voltammetry

Gas adsorption

Thermogravimetric analysis

ab initio and DFT computational methods

 

Current funding for research in the Zhou group comes from the following sources:

NSF Home Page

NSF CAREER Grant

Research Corporation: 2003 Research Innovation Award

Research Corporation: 2005 Cottrell Scholar Award

Air Products & Chemicals, Inc.: 2007 Faculty Excellence Award

Naval Surface Warfare Center, Crane Division

U.S. Department of Defense

U.S. Department of Energy

Ohio Board of Regents

Miami University

 

 

© 2008 Hongcai Joe Zhou All rights reserved